Chemical Name | 9-Borabicyclo[3.3.1]nonane |
CAS Number | 280-64-8 |
EC Number | 206-000-9 |
Beilstein Registry Number | 605509 |
MDL Number | MFCD00074742 |
Synonym |
9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
{} {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
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{} {} {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal
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PubChem Substance ID | 6327450 |
Chemical Name Translation | 9-硼雙環[3.3.1]壬烷 |
InChIKey | FEJUGLKDZJDVFY-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00222630 |
InChI | InChI=1S/C8H14B/c1-3-7-5-2-6-8(4-1)9-7/h7-8H,1-6H2 |
Canonical SMILES | C1(B2)CCCC2CCC1 |
Signal word |
Danger |
GHS Symbol
WGK Germany | 3 |
Safety Statements | |
- S16 Keep away from sources of ignition - No smoking 遠離火源,禁止吸煙;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后,立即用大量水沖洗并征求醫生意見;
- S30 Never add water to this product 切勿將水加入該產品中;
- S37/39 Wear suitable gloves and eye/face protection 穿戴適當的手套和眼睛/面保護;
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 著火時使用(指明具體的消防器材種類,如果用水增加危險,注明“禁止用水”
- S7/8 Keep container tightly closed and dry 保存在嚴格密閉容器中,保持干燥;
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Risk Statements | |
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水會猛烈反應
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水劇烈反應,釋放出高度可燃氣體
- R15 Contact with water liberates extremely flammable gases 遇水會釋放出極端易燃的氣體
- R19 May form explosive peroxides 可能生成易爆的過氧化物質
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮膚接觸和不慎吞咽有害
- R36/37 Irritating to eyes and respiratory system 對眼睛和呼吸系統有刺激性
- R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
- R38 Irritating to skin 刺激皮膚
- R40 Limited evidence of a carcinogenic effect 有限證據表明其致癌作用
- R48/20
- R51/53
- R62 Possible risk of impaired fertility 有削弱生殖能力的危險
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能傷害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能導致嗜睡和昏厥
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Precautionary statements | |
- P201 Obtain special instructions before use. 使用前獲取專門指示。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 遠離熱源/火花/明火/熱的表面。——禁止吸煙。
- P222 Do not allow contact with air. 不要與空氣接觸。
- P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 遠離任何與水接觸的可能,因為會劇烈反應可能產生閃火。
- P231+P232
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
- P264 Wash hands thoroughly after handling. 處理后要徹底洗凈雙手。
- P273 Avoid release to the environment. 避免釋放到環境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
- P301+P310
- P301+P330+P331
- P302+P334
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或醫生/醫師。
- P321 Specific treatment (see … on this label). 具體治療(見本標簽上的)。
- P331 Do NOT induce vomiting.. 不要催吐。
- P335+P334
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗凈后方可重新使用。
- P370+P378
- P402+P404
- P403+P235
- P405 Store locked up. 上鎖保管。
- P422 Store contents under… 存儲目錄在…之下。
- P501 Dispose of contents/container to..… 處理內容物/容器.....
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Hazard statements | |
- H225 Highly flammable liquid and vapour 高度易燃液體和蒸氣
- H250 Catches fire spontaneously if exposed to air 暴露于空氣自發著火
- H260 In contact with water releases flammable gases which may ignite spontaneously 與水接觸時釋放可燃氣體,可自燃。
- H304 May be fatal if swallowed and enters airways 吞食和進入呼吸道可能致命
- H314 Causes severe skin burns and eye damage 導致嚴重的皮膚灼傷和眼睛損傷
- H315 Causes skin irritation 會刺激皮膚
- H319 Causes serious eye irritation 嚴重刺激眼睛
- H335 May cause respiratory irritation 可能導致呼吸道刺激
- H336 May cause drowsiness or dizziness 肯能導致嗜睡或頭暈
- H351 Suspected of causing cancer 懷疑致癌
- H361 Suspected of damaging fertility or the unborn child 懷疑對生育能力或未出生嬰兒造成傷害
- H373 May causes damage to organs through prolonged or repeated exposure 長期或頻繁接觸可能會損傷器官
- H411 Toxictoaquaticlifewithlonglastingeffects 對水生生物有毒性并具有長期影響。
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Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Hazard Codes |
4.3
F,Xn
F,Xn,N
F,Xn,Xi,N
F;Xi |
UN Number |
3399 |
Packing Group | I |
Storage condition |
2-8°C
{LY} 2-8°C
Flammables area
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{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8° |
使用 9-BBN 對相應環狀縮醛進行還原以鑒別對稱二醇。
選擇性硼氫化還原試劑。
Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides
• Intramolecular insertion of alkenes into palladium-nitrogen bonds
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids