日本野外强奷在线播放VA_成人区亚洲区无码区在线_亚洲国产成人爱AV网站_亚洲成AV人片无码不卡

Phenylsilane 苯硅烷

規格: 99%, SpcSeal
CAS: 694-53-1
產品編號: H54060
MDL: MFCD00013478
品牌: INFI

簡介(jie)

有機硅烷類化合物主要應用在有機合成及有機硅材料領域。在有機合成中，硅烷作為羥基 保護基大量存在，如三甲基氯硅烷，TBSCI,有時作為一個合成子載體存在，如乙烯基三甲基 硅烷，烯丙基三甲基硅烷，六甲基二硅硫烷等，從而實現相應的官能團化反應。有機硅材料領域有硅烷偶聯劑、硅油（硅脂、硅乳液、硅表面活性劑）、高溫硫化硅橡膠、液體硅橡膠、硅 樹脂、封端劑，含硅復合共聚物等。

應用介紹及參考(kao)文獻

1.如乙烯(xi)基三甲基硅烷作為一個(ge)“乙烯(xi)”合成子，用于(yu)3+2環(huan)加(jia)成(cheng)反應，應用(yong)于有(you)機合成(cheng)過程中(zhong)。

圖片來源于期刊(kan)：Vinyltrimethylsilane, Glenn J. Fegley Gerald L. Larson, Encyclopedia of Reagents for Organic Synthesis, 2008.

2.如烯丙(bing)基(ji)三甲基(ji)硅烷，作為一(yi)個烯丙(bing)基(ji)化試劑，應用于艾日(ri)布林(lin)或者前列素類似物(wu)的合成中。

圖片來源于期刊：W020050118565, WO2019102490

圖片(pian)來(lai)源于期刊：Gary A. Sulikowski et al Org. Lett. 2019, 21, 10048-10051

3.作為聚合(he)引發劑(ji)(ji)，或者烯(xi)姪共聚物，參與烯(xi)姪聚合(he)，形成功(gong)能性有機硅材(cai)料，如耐水性硅膠 粘(zhan)合(he)劑(ji)(ji)，修飾聚氟乙(yi)烯(xi)等

技術優勢(shi)

產(chan)品(pin)純度高，具有百公斤生產(chan)能力(li)

Chemical NamePhenylsilane
MDL NumberMFCD00013478
EC Number211-772-5
CAS Number694-53-1
Synonym 苯基硅烷 phenyl-silane Monophenylsilane Phenylsilane Silane, phenyl- Phenylsilane, silyl- phenylsilane Silylbenzene 苯硅烷 Phenylsilane,97% Fenylsilan Benzene, silyl- PHENYLSILANE CHLORODIMETHYL phenyl-silan
Beilstein Registry Number2935169
PubChem Substance ID6327628
Reaxys-RN2935169
Chemical Name Translation苯硅烷
InChIKeyPARWUHTVGZSQPD-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007171
InChIInChI=1S/C6H5Si/c7-6-4-2-1-3-5-6/h1-5H
GHS Symbol
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 14500 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1227,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1227,1986

Safety Statements
  • S16 Keep away from sources of ignition - No smoking 遠離火源，禁止吸煙；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后，立即用大量水沖洗并征求醫生意見；
  • S36/37 Wear suitable protective clothing and gloves 穿戴適當的防護服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴適當的防護服、手套和眼睛/面保護；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 著火時使用（指明具體的消防器材種類，如果用水增加危險，注明“禁止用水”
  • S7/8 Keep container tightly closed and dry 保存在嚴格密閉容器中，保持干燥；
    UN Number 3399
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水劇烈反應，釋放出高度可燃氣體
    • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
    • R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
      Storage condition Moisture Sensitive Flammables area
      Signal word Danger
      WGK Germany3
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 遠離熱源/火花/明火/熱的表面。——禁止吸煙。
      • P231+P232
      • P233 Keep container tightly closed. ?保持容器密閉。
      • P240 Ground/bond container and receiving equipment. 與地面接觸/連接集裝箱和接受設備。
      • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆電氣/通風/照明/ .../設備。
      • P242 Use only non-sparking tools. 只能使用無火花工具。
      • P243 Take precautionary measures against static discharge. 采取預防措施，防止靜電放電。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
      • P264 Wash hands thoroughly after handling. 處理后要徹底洗凈雙手。
      • P264+P265
      • P270 Do not eat, drink or smoke when using this product. 使用本產品時不要吃東西，喝水或吸煙。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通風良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
      • P301+P312
      • P301+P312+P330
      • P301+P317
      • P302+P352
      • P302+P352+P332+P313+P362+P364
      • P303+
      • P303+P361+P353
      • P304+P312
      • P304+P340
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感覺不適，呼叫解毒中心或醫生/醫師。
      • P317
      • P319
      • P321 Specific treatment (see … on this label). 具體治療（見本標簽上的）。
      • P330 Rinse mouth. 漱口
      • P332+P313
      • P332+P317
      • P337+P313
      • P337+P317
      • P362 Take off contaminated clothing and wash before reuse. 脫掉污染的衣服，清洗后方可重新使用
      • P362+P364
      • P370+P378
      • P402+P404
      • P403+P233
      • P403+P235
      • P405 Store locked up. 上鎖保管。
      • P422 Store contents under… 存儲目錄在…之下。
      • P501 Dispose of contents/container to..… 處理內容物/容器.....
        Hazard statements
        • H225 Highly flammable liquid and vapour 高度易燃液體和蒸氣
        • H261 In contact with water releases flammable gas 與水接觸時釋放可燃氣體。
        • H302 Harmful if swallowed 吞食有害
        • H315 Causes skin irritation 會刺激皮膚
        • H319 Causes serious eye irritation 嚴重刺激眼睛
        • H332 Harmful if inhaled 吸入有害
        • H335 May cause respiratory irritation 可能導致呼吸道刺激
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          RTECSVV4825000
          Packing GroupII
          Hazard Codes 4.3 F,Xn Xn;F
          Hazard Class3
        • {uni_hamburg} Short: II/14a
        • Title: Molecular Constants: Diamagnetic Molecules
        • Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E.
        • Editor: Hellwege, K.-H.; Hellwege, A.M.
        • Source: Landolt-B?rnstein, New Series
        • Volume: II/14a
        • Page: 1-788
        • Year: 1982
        • Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy
        • ISBN: 3-540-11365-7
        • ISBN: 978-3-540-11365-2
        • Internet Resource: DOI:10.1007/b19966
        • RefComment: 196 figs., XI
        • {uni_hamburg} Short: II/2
        • Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds
        • Author: K?nig, E.
        • Editor: Hellwege, K.-H.; Hellwege, A.M.
        • Source: Landolt-B?rnstein, New Series
        • Volume: II/2
        • Year: 1966
        • ISBN: 3-540-03593-1
        • ISBN: 978-3-540-03593-0
        • Internet Resource: DOI:10.1007/b19948
        • RefComment: 170 figs., XII, 578 pages. Hardcover
        • Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
        • {uni_hamburg} Short: II/25D
        • Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms
        • Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
        • Editor: Kuchitsu, K.
        • Source: Landolt-B?rnstein, New Series
        • Volume: II/25D
        • Year: 2003
        • Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules
        • ISBN: 3-540-42860-7
        • ISBN: 978-3-540-42860-2
        • Internet Resource: DOI:10.1007/b75952
        • RefComment: VIII, 569 pages. Hardcover
        • RefComment: Written for scientists and researchers in the fields of chemistry and physics
        • Abstract: This fourth subvolume presents data on the geometric parameters (intern
          • 694-53-1 H54060 Phenylsilane 苯硅烷

          化學屬性

          Mol. FormulaC6H8Si
          Mol. Weight108.21
          Density0.88
          Flash Point8°C(lit.)
          TSCAYes
          Boiling Point120
          Refractive index1.5090 to 1.5120
          Melting Point-64 to -68°C
          Danger-Level甲類

          *以上化合物性質(zhi)及應(ying)用(yong)等信息僅供參考