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Allyltrimethylsilane 烯丙基三甲基硅烷

規格: 98%
CAS: 762-72-1
產品編號: H65036
MDL: MFCD00008635
品牌: INFI

簡介

有機硅烷類化合物主要應用在有機合成及有機硅材料領域。在有機合成中，硅烷作為羥基 保護基大量存在，如三甲基氯硅烷，TBSCI,有時作為一個合成子載體存在，如乙烯基三甲基 硅烷，烯丙基三甲基硅烷，六甲基二硅硫烷等，從而實現相應的官能團化反應。有機硅材料領域有硅烷偶聯劑、硅油（硅脂、硅乳液、硅表面活性劑）、高溫硫化硅橡膠、液體硅橡膠、硅 樹脂、封端劑，含硅復合共聚物等。

應用介紹(shao)及參考文獻

1.如乙(yi)烯基(ji)三甲(jia)基(ji)硅烷作為(wei)一個“乙(yi)烯”合成子，用于3+2環加(jia)成反應，應用于有機合成過程中。

圖片來源(yuan)于期刊：Vinyltrimethylsilane, Glenn J. Fegley Gerald L. Larson, Encyclopedia of Reagents for Organic Synthesis, 2008.

2.如(ru)烯(xi)丙基三甲基硅烷，作為一個(ge)烯(xi)丙基化(hua)試劑，應用于艾日(ri)布林或者前(qian)列素類似物(wu)的合(he)成中。

圖片來(lai)源于期刊(kan)：W020050118565, WO2019102490

圖片來源(yuan)于期刊：Gary A. Sulikowski et al Org. Lett. 2019, 21, 10048-10051

3.作為聚合引發劑，或者烯姪共(gong)聚物，參(can)與烯姪聚合，形成(cheng)功(gong)能(neng)性(xing)有機(ji)硅材料，如耐水性(xing)硅膠 粘合劑，修飾聚氟乙烯等

技術(shu)優勢

產品純度(du)高，具有(you)百公斤(jin)生產能力(li)

Chemical NameAllyltrimethylsilane
Synonym Allyltrimethylsilane {LY} Allyltrimethylsilane allyltrimethylsilane {} {LY} Allyltrimethylsilane {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyltrimethyl
MDL NumberMFCD00008635
CAS Number762-72-1
EC Number212-104-5
Beilstein Registry Number906755
PubChem Substance ID69808
Reaxys-RN906755
Chemical Name Translation烯丙基三甲基硅烷
LabNetwork Molecule IDLN00008514
InChIInChI=1S/C6H14Si/c1-5-6-7(2,3)4/h5H,1,6H2,2-4H3
Canonical SMILESC[Si](C)(C)CC=C
GHS Symbol
Signal word Danger
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 遠離火源，禁止吸煙；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入氣體/煙霧/蒸汽/噴霧；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后，立即用大量水沖洗并征求醫生意見；
  • S33 Take precautionary measures against static discharges 對靜電采取預防措施；
  • S36 Wear suitable protective clothing 穿戴適當的防護服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴適當的防護服、手套和眼睛/面保護；
  • S37 Wear suitable gloves 戴適當手套；
  • S9 Keep container in a well-ventilated place 保持容器在通風良好的場所；
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 遠離熱源/火花/明火/熱的表面。——禁止吸煙。
      • P233 Keep container tightly closed. ?保持容器密閉。
      • P240 Ground/bond container and receiving equipment. 與地面接觸/連接集裝箱和接受設備。
      • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆電氣/通風/照明/ .../設備。
      • P242 Use only non-sparking tools. 只能使用無火花工具。
      • P243 Take precautionary measures against static discharge. 采取預防措施，防止靜電放電。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
      • P264 Wash hands thoroughly after handling. 處理后要徹底洗凈雙手。
      • P264+P265
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通風良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
      • P302+P352
      • P302+P352+P312+P362+P364
      • P303+P361+P353
      • P304+P340
      • P305+P351+P338
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感覺不適，呼叫解毒中心或醫生/醫師。
      • P319
      • P321 Specific treatment (see … on this label). 具體治療（見本標簽上的）。
      • P332+P313
      • P332+P317
      • P337+P313
      • P337+P317
      • P362 Take off contaminated clothing and wash before reuse. 脫掉污染的衣服，清洗后方可重新使用
      • P362+P364
      • P370+P378
      • P403+P233
      • P403+P235
      • P405 Store locked up. 上鎖保管。
      • P501 Dispose of contents/container to..… 處理內容物/容器.....
        Packing GroupII
        UN Number 1993 UN 1993 3/PG 2
        Hazard statements
        • H225 Highly flammable liquid and vapour 高度易燃液體和蒸氣
        • H315 Causes skin irritation 會刺激皮膚
        • H319 Causes serious eye irritation 嚴重刺激眼睛
        • H335 May cause respiratory irritation 可能導致呼吸道刺激
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Hazard Codes 3 F;Xi
          Hazard Class3
          Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
        • 用于高分子有機硅化合物的合成
        • {ALF} Has also been used, in the presence of a catalyst such as p-TsOH, I2, Br2 or TfOH, as a silylating agent for alcohols, phenols and carboxylic acids: Tetrahedron Lett., 21, 835 (1980); J. Org. Chem., 46, 5212 (1981). The advantage over more conventional silylation methods is that the only by-product is the neutral gas propene.
        • {ALF} Reactions with electrophiles illustrate the ß-effect (see Appendix 4); e.g. acid chlorides with a Lewis acid give allyl ketones: J. Organomet. Chem., 85, 149 (1975):
        • {uni_hamburg} Short: III/35C4
        • {ALF} More recent studies have shown that TMS cyclopentanes are also formed in these reactions via a competing [3+2] cycloaddition mechanism: Tetrahedron, 49, 9955 (1993). Chemoselective addition to aldehydes can be accomplished in the presence of a ketone, using Scandium(III)­ trifluoromethanesulfonate hydrate, 40566 as catalyst: Synthesis, 1822 (1998).
        • {ALF} In the presence of F-, functions as an allyl anion equivalent, affording homoallylic alcohols from carbonyl compounds: Tetrahedron Lett., 3043 (1978), and adding to a variety of Michael acceptors: Tetrahedron Lett., 25, 3213 (1984); J. Org. Chem., 51, 1745 (1986). For a review of reactivity in the presence of Lewis acids and F-, see: J. Prakt. Chem./ Chem. Ztg., 336, 375 (1994).
        • {ALF} Similarly, carbonyl compounds are converted to homoallylic alcohols: J. Organomet. Chem., 69, C15 (1974). In the TiCl4 promoted reaction with enones, behaves as an allyl anion equivalent, giving the product of conjugate addition (Hosomi-Sakurai reaction): J. Am. Chem. Soc., 99, 1673 (1977); 105, 2354 (1983); Org. Synth. Coll., 7, 443 (1990):
        • {ALD} Merck: 14,10335
        • {uni_hamburg} Short: III/35F
        • {ALD} Merck: 14,10335
        • Beilstein:4(3)1854
          • 762-72-1 H65036 Allyltrimethylsilane 烯丙基三甲基硅烷

          化學屬性

          Mol. FormulaC6H14Si
          Mol. Weight114.26
          Density0.719
          Refractive index1.4060 to 1.4080
          Flash Point7°C(lit.)
          TSCAYes
          Boiling Point84-88 °C at 760 mmHg
          Solubility不溶
          Appearance 無色液體。沸點44℃（2.4kPa），相對密度1.1628（20/4℃），折光率1.4675（20℃）。能與有機溶劑混合，不溶于水。

          *以上化合物性質及(ji)應用等信息僅(jin)供(gong)參考