| Chemical Name | Vinylmagnesium bromide |
|---|
| CAS Number | 1826-67-1 |
|---|
| EC Number | 217-375-3 |
|---|
| Beilstein Registry Number | 3535841 |
|---|
| MDL Number | MFCD00000042 |
|---|
| Reaxys-RN | 3535841 |
|---|
| PubChem Substance ID | 87577845 |
|---|
| Synonym |
Norman reagent
Ethenylmagnesium bromide
Vinyl magnesium bromide
VINYLMAGNESIUM BROMIDE
Vinyl-magnesium bromide
0.98g/ml，20℃
VINYLMAGNESIUM BROMIDE SOLUTION, ~1.0 M IN THF
乙烯基溴化鎂四氫呋喃溶液
VINYLMAGNESIUMBROMICLC
Vinylmagnesium bromide
Bromovinylmagnesium
Vinylmagnesium bromide0.7M solution in THFAcroSeal§3
Vinylmagnesium bromide(1.0mol/Lsolytion in tetrahydro-furan)
Bromvinylmagnesium
bromoethenyl-magnesiu
Magnesium, bromovinyl-
Vinylmagnesium Bromide 0.7 M in Tetrahydrofuran
Vinylmagnesium bromide, 0.8-1.0 M in THF
乙烯基溴化鎂
Vinylmagnesium Bromide (14% in Tetrahydrofuran, ca. 1mol/L)
VINYLMAGNESIUM BROMIDE, 1.0M SOLUTION IN TETRAHYDROFURAN
溴化乙烯基鎂
乙烯基溴化鎂;溴化乙烯鎂
Vinylmagnesium bromide, 0.8-1.0 M in THF, packaged under Argon in resealable ChemSeal bottles
vinylmagnesiumbromidesolution
bromovinylmagnesium
溴化乙烯鎂
Vinylmagnesium bromide, 0.7M solution in THF
溴化乙烯鎂四氫呋喃溶液
溴化乙烯鎂(1MOL/L四氫呋喃溶液)
乙烯基溴化鎂 溶液
Magnesium, bromoethenyl- |
| Chemical Name Translation | 乙烯基溴化鎂 |
|---|
| InChIKey | XHHHAXOHMKAOSL-UHFFFAOYSA-M |
|---|
| LabNetwork Molecule ID | LN00223958 |
|---|
| Signal word |
Danger |
GHS Symbol
| WGK Germany | 1 |
|---|
| Safety Statements | |
|---|
- S16 Keep away from sources of ignition - No smoking 遠離火源，禁止吸煙；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后，立即用大量水沖洗并征求醫生意見；
- S29 Do not empty into drains 不要排入下水道；
- S33 Take precautionary measures against static discharges 對靜電采取預防措施；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴適當的防護服、手套和眼睛/面保護；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 著火時使用（指明具體的消防器材種類，如果用水增加危險，注明“禁止用水”
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不適時，立即求醫（可能時出示標簽）；
- S6 Keep under ... (inert gas to be specified by the manufacturer) 將該物質保存在生產廠家指定的惰性氣體中；
|
| Risk Statements | |
|---|
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水會猛烈反應
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水劇烈反應，釋放出高度可燃氣體
- R19 May form explosive peroxides 可能生成易爆的過氧化物質
- R34 Causes burns 會導致灼傷
- R37 Irritating to respiratory system 刺激呼吸道
- R40 Limited evidence of a carcinogenic effect 有限證據表明其致癌作用
|
| Precautionary statements | |
|---|
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 遠離熱源/火花/明火/熱的表面。——禁止吸煙。
- P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 遠離任何與水接觸的可能，因為會劇烈反應可能產生閃火。
- P231+P232
- P233 Keep container tightly closed. ?保持容器密閉。
- P240 Ground/bond container and receiving equipment. 與地面接觸/連接集裝箱和接受設備。
- P241+
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
- P264 Wash hands thoroughly after handling. 處理后要徹底洗凈雙手。
- P270 Do not eat, drink or smoke when using this product. 使用本產品時不要吃東西，喝水或吸煙。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通風良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
- P301+P330+P331+P310
- P303+P361+P353
- P304+P340
- P304+P340+P310
- P305+P351+P338+P310
- P308+P311
- P335+P334
- P370+P378
- P403+P233
- P422 Store contents under… 存儲目錄在…之下。
- P501 Dispose of contents/container to..… 處理內容物/容器.....
|
| Storage condition |
0-10
儲存溫度2-8℃,充氬保存
儲存溫度2-8°C
0-10°C
Refrigerator |
| UN Number |
3399 |
| Hazard statements | |
|---|
- H314 Causes severe skin burns and eye damage 導致嚴重的皮膚灼傷和眼睛損傷
- H351 Suspected of causing cancer 懷疑致癌
- H260 In contact with water releases flammable gases which may ignite spontaneously 與水接觸時釋放可燃氣體，可自燃。
- H225 Highly flammable liquid and vapour 高度易燃液體和蒸氣
- H335 May cause respiratory irritation 可能導致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
|
| Personal Protective Equipment |
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes |
4.3
F,C |
| Packing Group | II |
|---|
| Hazard Class | 4.3/3 |
|---|
| Restrict |
- |
⑴. 由于鎂原子直接和碳鏈相連，極化作用使鄰近鎂原子的那個碳原子呈負電性，使得C-Mg鍵極具反應活性。為了保證該產品不發生其他反應，反應一般在醚類溶劑里進行,常用的有乙醚或四氫呋喃。
⑵. 有強烈的親核性質，可與物質中的活潑氫（如水、乙醇的羥基氫、乙炔的末端氫）反應,生成相應的烴基。
⑶. 與CO2或O2的反應，可以與二氧化碳或氧氣發生親核加成反應生成增加一個碳的羧酸或同碳數的過氧化合物.格氏試劑與二氧化碳的加成反應在有機合成中也有著重要的意義,不僅通過生成新的 C-C 鍵實現了碳鏈的增長,而且恰到好處地
{SA}
Aldrich MSDS 1 , 1837:D / Corp MSDS 1 (2), 3605:B / Structure Index 1 , 483:B:6
{uni_hamburg} Short: III/35C4
Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds
Author: Gupta, R.R.; Platzer, N.
Editor: Gupta, R.R.; Lechner, M.D.
Source: Landolt-B?rnstein, New Series
Volume: III/35C4
Year: 2001
Keyword: Hydrogen 1; Nuclear Magnetic Resonance
ISBN: 3-540-41059-7
ISBN: 978-3-540-41059-1
Internet Resource: DOI:10.1007/b76570
RefComment: VII, 299 pages. With CD-ROM. Hardcover
Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
{uni_hamburg} Short: EINECS
Title: EINECS (European Inventory of Existing Commercial Chemical Substances)
Source: Official Journal of the European Communities
Volume: C 146 A (15.06.1990)
Page: 1
Year: 1990
Internet Resource: //ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein
Publish_Date: 1990/06/15
